Molecular Materials Group
School of Chemistry
University of Sydney
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Publications

2018

  1. J.E. Clements, P.R. Airey, F. Ragon, V. Shang, C.J. Kepert and S.M. Neville, Guest-Adaptable Spin Crossover Properties in a Dinuclear Species Underpinned by Supramolecular Interactions, Inorg. Chem. 2018, 57, 14930-14938. doi: 10.1021/acs.inorgchem.8b02625

  2. A.R. Craze, M.M. Bhadhade, C.J. Kepert, L.F. Lindoy, C.E. Marjpo and F. Li, Solvent Effects on the Spin-Transition in a Series of Fe(II) Dinuclear Triple Helicate Compounds, Crystals 2018, 8, 376/1-376/16. doi: 10.3390/cryst8100376

  3. D.Z.T. Mulrooney, J.E. Clements, D.J. Ericsson, J.R. Price, I.A. Kuehne, S.J. Coles, C.J. Kepert and T.D. Keene, Phase Control of Ferromagnetic Copper(II) Carbonate Coordination Polymers through Reagent Concentration, Eur. J. Inorg. Chem. 2018, 48, 5223-5228. doi: 10.1002/ejic.201801041

  4. J.E. Auckett, A.A. Barkhordarian, S.H. Ogilvie, S.G. Duyker, H. Chevreau, V.K. Peterson and C.J. Kepert, Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks, Nat. Commun. 2018, 9, 4873. doi: 10.1038/s41467-018-06850-6

  5. G. Chastanet, N.F. Sciortino, S.M. Neville, C.J. Kepert, High Spin to Low Spin Relaxation Regime Change in a Multistep 3D Spin-Crossover Material, Eur. J. Inorg. Chem., 2018, 54(11), 1363-1366. doi:10.1002/ejic.201701127

  6. K.A. Zenere, S.G. Duyker, E. Trzop, E. Collet, B. Chan, P.W. Doheny, C.J. Kepert and S.M. Neville, Increasing spin crossover in 2D Hofmann-type materials with guest molecule removal, Chem. Sci. 2018, 9(25), 5623-5629. doi: 10.1039/C8SC01040D

  7. A.R. Craze, K.J. Howard-Smith, M.M. Bhadbhade, O. Mustonen, C.J. Kepert, C.E. Marjo, F. Li, Investigation of the High-Temperature Spin-Transition of a Mononuclear Iron(II) Complex Using X-ray Photoelectron Spectroscopy, Inorg. Chem., 2018, 57(11), 6503-6510. doi: 10.1021/acs.inorgchem.8b00576

  8. R.J. Walwyn, B. Chan, P.M. Usov, M.B. Solomon, S.G. Duyker, J.Y Koo, P. Turner, C.J. Kepert, D.M. D'Alessandro Spectroscopic, electronic and computational properties of a mixed tetrachalcogenafulvalene and its charge transfer complex, J. Mater. Chem. C, 2018, 6(5), 1092-1104. doi: 10.1039/C7TC03853D

  9. C. Hua, P.W. Doheny, B. Ding, M. Yu, C.J. Kepert and D.M. D'Alessandro, Through-Space Intervalence Charge Transfer as a Mechanism for Charge Delocalization in Metal-Organic Frameworks, J. Am. Chem. Soc. 2018, 140(21), 6622-6630. doi: 10.1021/jacs.8b02638

2017

  1. B.R. Mullaney, L. Goux-Capes, D.J. Price, G. Chastanet, J.-F. Letard, C.J. Kepert, Spin crossover-induced colossal positive and negative thermal expansion in a nanoporous coordination framework material, Nature Commun., 2017, 8(1), 1053-1059. doi:10.1038/s41467-017-00776-1

  2. A.R. Craze, N.F. Sciortino, M.M. Badbhade, C.J. Kepert, C.E. Marjo, F. Li Investigation of the Spin Crossover Properties of Three Dinulear Fe(II) Triple Helicates by Variation of the Steric Nature of the Ligand Type, Inorganics, 2017, 5(4), 62. doi:10.3390/inorganics5040062

  3. L. Li, S.M. Neville, A.R. Craze, J.K. Clegg, N.F. Sciortino, K.S. Athukorala Arachchige, O. Mustonen, C.E. Marjo, C.R. McRae, C.J. Kepert, L.F. Lindoy, J.R. Aldrich-Wright, F. Li, Spin-State Patterning in an Iron(II) Tripodal Spin-Crossover Complex, ACS Omega, 2017, 2(7), 3349-3353. doi:10.1021/acsomega.7b00630

  4. B.F. Abrahams, A.D. Dharma, P.S. Donnelly, T.A. Hudson, C.J. Kepert, R. Robson, P.D. Southon, K.F. White, Tunable Porous Coordination Polymers for the Capture, Recovery and Storage of Inhalation Anesthetics, Chem. Eur. J., 2017, 23(33), 7871-7875. doi: 10.1002/chem.201700389

  5. M.A.D. Roxburgh, S. Zaiter, X.I.B. Hudson, B.R. Mullaney, J.E. Clements, B. Moubaraki, K.S. Murray, S.M. Neville, C.J. Kepert, Structure and Magnetic Studies on a Series of Two-Dimensional Iron(II) Framework Materials with Varying Ligand Characteristics, Aust. J. Chem., 2017, 70(5), 623-631. doi:doi.org/10.1071/CH16586

  6. A.A. Barkhordarian, C.J. Kepert, Two new porous UiO-66-type zirconium frameworks; open aromatic N-donor sites and their post-synthetic methylation and metallation, J. Mater. Chem. A, 2017, 5, 5612-5618. doi:10.1039/C6TA11005C

  7. M.R. Bryant, A.D.Burrows, C.J. Kepert, P.D Southon, O.T. Qazvini, S.G. Telfer, C. Richardson, Mixed-Component Sulfone-Sulfoxide Tagged Zinc IRMOFs: In Situ Ligand Oxidation, Carbon Dioxide, and Water Sorption Studies, Cryst. Growth Des., 2017, 17(4), 2016-2023. doi:10.1021/acs.cgd.7b00007

  8. M.J. Murphy, K.A. Zenere, F. Ragon, P.D. Southon, C.J. Kepert and S.M. Neville, Guest Programmable Multistep Spin Crossover in a Porous 2-D Hofmann-Type Material, J. Am. Chem. Soc. 2017, 139, 1330-1335. doi: 10.1021/jacs.6b12465

  9. N.F. Sciortino, K.A. Zenere, M.E. Corrigan, G.J. Halder, G. Chastanet, J.F. Létard, C.J. Kepert and S.M. Neville, Four-step iron(II) spin state cascade driven by antagonistic solid state interactions, Chem. Sci., 2017, 8, 701-707. doi:10.1039/C6SC03114E

2016

  1. J.E. Auckett, S.H. Ogilvie, S.G. Duyker, P.D. Southon, C.J. Kepert, V.K. Peterson, Flexible yttrium coordination geometry inhibits “bare-metal” guest-interactions in the metal-organic framework Y(btc), Energies, 2016, 9(10), 836. doi:10.3390/en9100836

  2. N.F. Sciortino, F. Ragon, K.A. Zenere, P.D. Southon, G.J. Halder, K.W. Chapman, L. Piñeiro-López, J.A. Real, C.J. Kepert and S.M. Neville, Exploiting Pressure To Induce a “Guest-Blocked” Spin Transition in a Framework Material, Inorg. Chem., 2016, 55, 10490-10498. doi:10.1021/acs.inorgchem.6b01686

  3. R.G. Miller, P.D. Southon, C.J. Kepert and S. Brooker, Commensurate CO2 capture, and shape selectivity for HCCH over H2CCH2, in zigzag channels of a robust CuI(CN)(L) MOF, Inorg. Chem., 2016, 55(12) 6195–6200 doi:10.1021/acs.inorgchem.6b00813

  4. S.G. Duyker, V.K. Peterson, G.J. Kearley, A.J. Studer and C.J. Kepert, Extreme compressibility in LnFe(CN)6 coordination framework materials via molecular gears and torsion springs, Nature Chem., 2016, 8, 270–275. DOI:10.1038/nchem.2431

  5. J.E. Clements, J.R. Price, S.M. Neville and C.J. Kepert, Hysteretic Four-Step Spin Crossover within a Three Dimensional Porous Hofmann-like Material, Angew. Chem. Int. Ed. 2016, 55, 15105-15109. DOI:10.1002/anie.201605418

  6. Y.M. Klein, N.F. Sciortino, C.E. Housecroft, C.J. Kepert and S.M. Neville, Structure and magnetic properties of the spin crossover linear trinculear complex [Fe3(furtrz)6(ptol)2(MeOH)]•4(ptol)4(MeOH) (furtrz: furanylidene-4H-1,2,4-triazol-4-amine, ptol = p-tolylsulfonate), Magnetochemistry 2016, 2(1), 1–8. DOI:10.3390/magnetochemistry2010007

2015

  1. B. Nafradi, M. Choucair, P.D. Southon, C.J. Kepert, L. Forro, Strong interplay between the electron spin lifetime in chemically synthesized graphene multilayers and surface-bound oxygen, Chem. Eur. J., 2015, 21(2), 770-777. DOI: 10.1002/anie.201204387 [Highlighted article with journal cover picture]

  2. A. Das, P.D. Southon, C.J. Kepert, D.M. D’Alessandro, Carbon Dioxide Adsorption via Physisorption and Chemisorption Interactions in Piperazine-Grafted Ni2(dobdc) (dobdc = 1,4-dioxido-2,5-benzenedicarboxylate), Dalton Trans., 2012, 41(38), 11739-11744. DOI: 10.1039/C2DT31112G

  3. P. Yuan, P.D. Southon, Z. Liu, C.J. Kepert, Organosilane functionalization of halloysite nanotubes for enhanced loading and controlled release of Orange II, Nanotech., 2012, 23(37), 375705. DOI:

2014

  1. N.F. Sciortino, S.M. Neville, C. Desplanches, J-F. Létard, V. Martinez, J. Real, B. Moubaraki, K. Murray, C.J. Kepert, An investigation of photo- and pressure-induced effects in a pair of isostructural two-dimensional spin-crossover framework materials, Chem. Eur J., 2014, 20(24), 7448-7457. DOI: 10.1002/chem.201400367

  2. F. Rizzuto, T. Faust, B. Chan, C. Hua, D.M. D'Alessandro, C.J. Kepert, Experimental and computational studies of a multi-electron donor-acceptor ligand containing the thiazolo[5,4-d]thiazole core and its incorporation into a metal-organic framework, Chem. Eur J., 2014, 20(52), 17597-17605. DOI: 10.1002/chem.201405089

  3. A. Yuan, H. Zhou, G. Diao, P.D. Southon, C.J. Kepert, L. Liu, Gas and vapor adsorption in octacyanometallate-based frameworks Mn2[M(CN)8] (M = W, Mo) with exposed Mn2+ sites, Int. J. Hydrogen. Energ., 2014, 39(2), 884-889. DOI: 10.1016/j.ijhydene.2013.10.143

  4. V.K. Peterson, P.D. Southon, G. Halder, D. Price, J. Bevitt, C.J. Kepert, Guest Adsorption in the Nanoporous Metal-Organic Framework Cu3(1,3,5-Benzenetricarboxylate)2: Combined In Situ X-ray Diffraction and Vapor Sorption, Chem. Mater., 2014, 26(16), 4712-4723. DOI: 10.1021/cm501138g

  5. T. Faust, P. Usov, D.M. D'Alessandro, C.J. Kepert, Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks, Chem. Commun., 2014, 50(84), 12772-12774. DOI: 10.1039/C4CC05438E

  6. S. Ogilvie, S. Duyker, P.D. Southon, V.K. Peterson, C.J. Kepert, Host-guest adsorption behavior of deuterated methane and molecular oxygen in a porous rare-earth metal-organic framework, Powder Diffr., 2014, 29(S1), S96-S101. DOI: 10.1017/S0885715614001158

  7. Y. Wu, V.K. Peterson, E. Luks, T. Darwish, C.J. Kepert, Interpenetration as a Mechanism for Negative Thermal Expansion in the Metal–Organic Framework Cu3(btb)2 (MOF-14), Angew. Chem. Int. Ed., 2014, 53(20), 5175–5178. DOI: 10.1002/anie.201311055

  8. M. Murphy, T. Keene, J. Price, D.M. D'Alessandro, C.J. Kepert, Magnetic and electronic properties of three new hetero-bimetallic coordination frameworks [Ru2(02CR)4][Au(CN)2] (R = benzoic acid, Furan-2-carboxylate, or Thiophen-2-carboxylate), Aust. J. Chem., 2014, 67(11), 1607-1611. DOI: 10.1071/CH14196

  9. M. Murphy, P. Usov, F. Rizzuto, C.J. Kepert, D.M. D'Alessandro, Magnetic, electrochemical and optical properties of a sulfate-bridged Co(II) imidazole dimer, New J. Chem., 2014, 38(12), 5856-5860. DOI: 10.1039/C4NJ01401D

  10. T. Keene, M. Murphy, J. Price, N.F. Sciortino, P.D. Southon, C.J. Kepert, Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption, Dalton Trans., 2014, 43(39), 14766-14771. DOI: 10.1039/C4DT02205J

  11. J. Sundberg, L. Cameron, P.D. Southon, C.J. Kepert, C. McKenzie, Oxygen chemisorption/desorption in a reversible single-crystal-to-single-crystal transformation, Chem. Sci., 2014, 5(10), 4017-4025. DOI: 10.1039/C4SC01636J

  12. J. Clements, J. Price, S.M. Neville, C.J. Kepert, Perturbation of Spin Crossover Behavior by Covalent Post-Synthetic Modification of a Porous Metal-Organic Framework, Angew. Chem. Int. Ed., 2014, 53(38), 10164-10168. DOI: 10.1002/anie.201402951

  13. M. Cowan, R. Miller, P.D. Southon, J. Price, O. Yazaydin, J. Lane, C.J. Kepert, S. Brooker, Selective Gas Adsorption in a Pair of Robust Isostructural MOFs Differing in Framework Charge and Anion Loading, Inorg. Chem., 2014, 53(22), 12076-12083. DOI: 10.1021/ic501876m

  14. F. Reichel, J. Clegg, K. Gloe, J. Weigand, J. Reynolds, C. Li, J. Aldrich-Wright, C.J Kepert, L. Lindoy, H-C. Yao, L. Feng, Self-assembly of an imidazolate-bridged Fe(III)/Cu(II) heterometallic cage, Inorg. Chem., 2014, 53(2), 688-690. DOI: 10.1021/ic402686s

  15. F. Li, N.F. Sciortino, J. Clegg, S.M. Neville, C.J. Kepert, Self-Assembly of an Octanuclear High-Spin FeII Molecular Cage, Aust. J. Chem., 2014, 67(11), 1625-1628. DOI: 10.1071/CH14404

  16. M. Klein, N.F. Sciortino, F. Ragon, C. Housecroft, C.J. Kepert, S.M. Neville, Spin crossover intermediate plateau stabilization in a flexible 2-D Hofmann-type coordination polymer, Chem. Commun., 2014, 50(29), 3838-3840. DOI: 10.1039/C4CC01079E

  17. B. Pages, F. Li, P. Wormell, D. Ang, J. Clegg, C.J. Kepert, L. Spare, S. Danchaiwijit, J. Aldrich-Wright, Synthesis and analysis of the anticancer activity of platinum(II) complexes incorporating dipyridoquinoxaline variants, Dalton Trans., 2014, 43(41), 15566-15575. DOI: 10.1039/C4DT02133A

  18. F. Ragon, K. Yaksi, N.F. Sciortino, G. Chastanet, J-F Létard, D.M. D'Alessandro, C.J. Kepert, S.M. Neville, Thermal spin crossover behaviour of two-dimensional Hofmann-type coordination polymers incorporating photoactive ligands, Aust. J. Chem., 2014, 67(11), 1563-1573. DOI: 10.1071/CH14188

  19. N.F. Sciortino, S.M. Neville, J. Létard, B. Moubaraki, K. Murray, C.J. Kepert, Thermal- and light-induced spin-crossover bistability in a disrupted Hofmann-type 3D framework, Inorg. Chem., 2014, 53(15), 7886-7893. DOI: 10.1021/ic500323r

  20. S.G. Duyker, G.J. Halder, P.D. Southon, D. Price, A. Edwards, V.K. Peterson, C.J. Kepert, Topotactic structural conversion and hydration-dependent thermal expansion in robust LnMIII(CN)6 •nH2O and flexible ALnFeII(CN)6•nH2O frameworks (A = Li, Na, K; Ln = La-Lu, Y; M = Co, Fe; 0 = n = 5), Chem. Sci., 2014, 5(9), 3409-3417. DOI: 10.1039/C4SC00809J

2013

  1. S.M. Neville, G.J. Halder, K. Murray, B. Moubaraki, C.J. Kepert, A family of three-dimensional molecular framework materials containing the three-connecting ligands 2,4,6-tris(n'-pyridyl)-1,3,5-triazine: 3-tpt and 4-tpt, Aust. J. Chem., 2013, 66(4), 452-463. DOI: 10.1071/CH12444

  2. M.J. Murphy, D.M. D'Alessandro, C.J. Kepert, A porous Mn(v) coordination framework with PtS topology: assessment of the influence of a terminal nitride on CO2 sorption, Dalton Trans., 2013, 42(37), 11739-11744. DOI: 10.1039/C3DT51721G

  3. A. Das, M. Choucair, P.D. Southon, J. Mason, M. Zhao, C.J. Kepert, A. Harris, D.M. D'Alessandro, Application of the piperazine-grafted CuBTTri metal-organic framework in postcombustion carbon dioxide capture, Microporous Mesoporous Mater., 2013, 174, 74-80. DOI: 10.1016/j.micromeso.2013.02.036

  4. R. Lyndon, K. Konstas, B. Ladewig, P.D. Southon, C.J. Kepert, M. Hill, Dynamic Photo-Switching in Metal-Organic Frameworks as a Route to Low-Energy Carbon Dioxide Capture and Release, Angew. Chem. Int. Ed., 2013, 52(13), 3695-3698. DOI: 10.1002/anie.201206359

  5. N. Lock, M. Christensen, C.J. Kepert, B. Iversen, Effect of gas pressure on negative thermal expansion in MOF-5, Chem. Commun., 2013, 49(8), 789-791. DOI: 10.1039/C2CC37415C

  6. C.F. Leong, T.B. Faust, P. Turner, P. Usov, C.J. Kepert, R. Babarao, A. Thornton,D. M. D'Alessandro, Enhancing selective CO2 adsorption via chemical reduction of a redox-active metal-organic framework, Dalton Trans., 2013, 42(27), 9831-9839. DOI: 10.1039/C3DT00083D

  7. S. Ogilvie, S.G. Duyker, P.D. Southon, V.K. Peterson, C.J. Kepert, Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction, Chem. Commun., 2013, 49(82), 9404-9406. DOI: 10.1039/C3CC46019C

  8. S.G. Duyker, V.K. Peterson, G. Kearley, A. Ramirez-Cuesta, C.J. Kepert, Negative thermal expansion in LnCo(CN)6 (Ln=La, Pr, Sm, Ho, Lu, Y): Mechanisms and compositional trends, Angew. Chem. Int. Ed., 2013, 52(20), 5266-5270. DOI: 10.1002/anie

  9. N. Lock, M. Christensen, Y. Wu, V.K. Peterson, M. Thomsen, R. Piltz, A. Ramirez-Cuesta, G. McIntyre, K. Norén, R. Kutteh, C.J. Kepert, G.J. Kearley, B.B. Iversen, Scrutinizing negative thermal expansion in MOF-5 by scattering techniques and ab initio calculations, Dalton Trans., 2013, 42(6), 1996-2007. DOI: 10.1039/C2DT31491F

  10. T. Keene, D. Rankine, J. Evans, P.D. Southon, C.J. Kepert, J. Aitken, C. Sumby, C. Doonan, Solvent-modified dynamic porosity in chiral 3D kagome frameworks, Dalton Trans., 2013, 42(22), 7871-7879. DOI: 10.1039/C3DT00096F

2012

  1. N.F. Sciortino, K.R. Scherl-Gruenwald, G. Chastanet, G.J. Halder, K.W. Chapman, J.-F. Létard, C.J. Kepert, Hysteretic three-step spin crossover in a thermo- and photo-chromic 3D pillared Hofmann-type metal-organic framework, Angew. Chem. Int. Ed., 2012, 51(40), 10154-10158. DOI: 10.1002/anie.201204387 Highlighted article with journal cover picture .

  2. A. Das, P.D. Southon, C.J. Kepert, D.M. D’Alessandro, Carbon Dioxide Adsorption via Physisorption and Chemisorption Interactions in Piperazine-Grafted Ni2(dobdc) (dobdc = 1,4-dioxido-2,5-benzenedicarboxylate), Dalton Trans, 2012, 41(38), 11739-11744. DOI: 10.1039/C2DT31112G

  3. P. Yuan, P.D. Southon, Z. Liu, C.J. Kepert, Organosilane functionalization of halloysite nanotubes for enhanced loading and controlled release of Orange II, Nanotech., 2012, 23(37), 375705. DOI:

  4. M.B. Duriska, S.M. Neville, B. Moubaraki, K.S. Murray, C. Balde, J.-F. Létard, C.J. Kepert, S.R. Batten, A Family of Discrete Magnetically Switchable Nanoballs, ChemPlusChem, 2012, 77(8), 616-623. DOI: 10.1002/cplu.201200123

  5. T.D. Keene, D.M. D’Alessandro, K.W. Krämer, J.R. Price, D.J. Price, S. Decurtins, C.J. Kepert, [V16O38(CN)]9: A Soluble Mixed-Valence Redox-Active Building Block with Strong Antiferromagnetic Coupling, Inorg. Chem., 2012, 51(17), 9192-9199. DOI: 10.1021/ic3001834

2011

  1. F. Li, J.K. Clegg, D.M. D'Alessandro, L. Goux-Capes, N.F. Sciortino, T.D. Keene, C.J. Kepert, Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5´,6´-pyrazine, Dalton Trans., 2011, 40 (45), 12388-12393. DOI: 10.1039/c1dt11254f

  2. F. Li, J.K. Clegg, C.J. Kepert, Structural diversity in coordination polymers constructed from a naphthalene-spaced dipyridyl ligand and iron(II) thiocyanate, J. Incl. Phenom. Macro., 2011, 71(3-4), 381-388. DOI: 10.1007/s10847-011-0016-5

  3. Y. Mulyana, L.F. Lindoy, C.J. Kepert, J. McMurtrie, A. Parkin, P. Turner, G. Wei, J. G. Wilson, New metal organic frameworks incorporating the ditopic macrocyclic ligand dipyridyldibenzotetraaza[14]annulene, J. Incl. Phenom. Macro., 2011, 71(3-4), 455-462. DOI: 10.1007/s10847-011-0007-6

  4. T.D. Keene, M.J. Murphy, J.R. Price, D.J. Price, C.J. Kepert, A new modification of an old framework: Hofmann layers with unusual tetracyanidometallate groups, Dalton Trans., 2011, 40(43), 11621-11628. DOI: 10.1039/c1dt11183c

  5. M.T. Dunstan, P.D. Southon, C.J Kepert, J. Hester, J.A. Kimpton, C.D. Ling, Phase diagram, chemical stability and physical properties of the solid-solution Ba4Nb2-xTaxO9, J Solid. State Chem., 2011, 184(10), 2648-2654. DOI: 10.1016/j.jssc.2011.07.036

  6. P.D. Southon, D.J. Price, P.K. Nielsen, C.J. McKenzie, C.J. Kepert, Reversible and selective O2 chemisorption in a porous metal–organic host material, J. Am. Chem. Soc., 2011, 133(28), 10885-10891. DOI: 10.1021/ja202228v

  7. T.D. Keene, D.J. Price, C.J. Kepert, Laboratory-based separation techniques for insoluble compound mixtures: Methods for the purification of metal-organic framework materials, Dalton Trans., 2011, 40(27), 7122-7126. DOI: 10.1039/c1dt10251f

  8. V.K. Peterson, C.M. Brown, Y. Liu, C.J. Kepert, Structural study of D2 within the trimodal pore system of a metal organic framework, J. Phys. Chem. C, 2011, 115(17), 8851-8857. DOI: 10.1021/jp2010937

  9. F. Li, J.K. Clegg, L. Goux-Capes, G. Chastanet, D.M. D'Alessandro, J-F. Létard, C.J. Kepert, A mixed-spin molecular square with a hybrid [2x2]grid/metallocyclic architecture, Angew. Chem. Int. Ed., 2011, 50(12), 2820-2823. DOI: 10.1002/anie.201007409

  10. C.J. Kepert. Metal-organic framework materials. Book chapter in: Porous Materials. ISBN: 978-0-470-99749-9. Editors: Bruce, DW; O'Hare, D and Walton, RI. Published by John Wiley & Sons, Ltd, Chapter 1, pp. 1-67, 2011.

  11. F. Li, J.K. Clegg, D. Price, C.J. Kepert, Self-assembly of a metallomacrocycle templated by iron(II), Inorg. Chem., 2011, 50(3), 726-728. DOI: 10.1021/ic102350t

2010
  1. N. Lock, Y. Wu, M. Christensen, S.L. Cameron, V.K. Peterson, A.J Bridgeman, C.J. Kepert, B.B. Iversen, Elucidating negative thermal expansion in MOF-5, J. Phys. Chem. C, 2010, 114(39), 16181-16186. DOI: 10.1021/jp103212z

  2. A-H. Yuan, P.D. Southon, D.J. Price, C.J. Kepert, H. Zhou, W-Y. Liu, Syntheses, crystal structures, and the phase transformation of octacyanometallate-based LnIII–WV bimetallic assemblies with two-dimensional corrugated layers, Eur. J. Inorg. Chem., 2010, (23), 3610-3614. DOI: 10.1002/ejic.201000320

  3. H. Wu, J.M. Simmons, Y. Liu, C.M. Brown, X-S. Wang, S. Ma, V.K. Peterson, P.D. Southon, C.J. Kepert, H-C. Zhou, T. Yildirim, W. Zhou, Metal-organic frameworks with exceptionally high methane uptake: Where are how is methane stored?, Chem. Eur. J., 2010, 16(17), 5205-5214. DOI: 10.1002/chem.200902719

  4. V.K. Peterson, G.J. Kearley, Y. Wu, A.J. Ramirez-Cuesta, E. Kemner, C.J. Kepert, Local vibrational mechanism for negative thermal expansion: A combined neutron scattering and first-principles study, Angew. Chem. Int. Ed., 2010, 49(3), 585-588, 2010. DOI: 10.1002/anie.200903366

  5. A.E. Phillips, G.J. Halder, K.W. Chapman, A.L. Goodwin, C.J. Kepert, Zero thermal expansion in a flexible, stable framework: Tetramethylammonium copper(I) zinc(II) cyanide, J. Am. Chem. Soc., 2010, 132(1), 10-11. DOI: 10.1021/ja906895j

  6. J.K. Clegg, S.S. Iremonger, M.J. Hayter, P.D. Southon, R.B. Macquart, M.B. Duriska, P. Jensen, P. Turner, K.A. Jolliffe, C.J. Kepert, G.V. Meehan, L.F. Lindoy, Hierarchical self-assembly of a chiral metal-organic framework displaying pronounced porosity, Angew. Chem. Int. Ed., 2010, 49(6), 1075-1078. DOI: 10.1002/anie.200905497

  7. J.J.M. Amoore, S.M. Neville, B. Moubaraki, S.S. Iremonger, K.S. Murray, J-F. Létard, C.J.K Kepert, Thermal- and light-induced spin crossover in a guest-dependent dinuclear iron(II) system, Chem. Eur. J., 2010, 16(6), 1973-1982. DOI: 10.1002/chem.200901809

2009
  1. M.B. Duriska, S.M. Neville, J. Lu, S.S. Iremonger, J.F. Boas, C.J. Kepert, S.R. Batten, Systematic metal variation and solvent and hydrogen-gas storage in supramolecular nanoballs, Angew. Chem. Int. Ed., 2009, 48(47), 8919-8922. DOI: 10.1002/anie.200903863

  2. C.J. Kepert, Supramolecular magnetic materials, Aust. J. Chem., 2009, 62(9), 1079-1080. DOI: 10.1071/CH09399

  3. S.M. Neville, G.J. Halder, K.W. Chapman, M.B. Duriska, B. Moubaraki, K.S. Murray, C.J. Kepert. Guest tunable structure and spin crossover properties in a nanoporous coordination framework material. J. Am. Chem. Soc., 2009, 131(34), 12106-12108. DOI: 10.1021/ja905360g

  4. P.D. Southon, L. Liu, E.A. Fellows, D.J. Price, G.J. Halder, K.W. Chapman, B. Moubaraki, K.S. Murray, J-F. Létard, C.J. Kepert, Dynamic interplay between spin-crossover and host-guest function in a nanoporous metal-organic framework material, J. Am. Chem. Soc., 2009, 131(31), 10998-11009.DOI: 10.1021/ja902187d

  5. H. Kumagai, M. Akita-Tanaka, S. Kawata, K. Inoue, C.J. Kepert, M. Kurmoo, Synthesis, crystal structures, and properties of molecular squares displaying hydrogen and pi-pi bonded networks, Cryst. Growth Des., 2009, 9(6), 2734-2741. DOI: 10.1021/cg801369u

  6. A.L. Goodwin, B.J. Kennedy, C.J. Kepert, Thermal expansion matching via framework flexibility in zinc dicyanometallates, J. Am. Chem. Soc., 2009, 131 (18), 6334. DOI: 10.1021/ja901355b

  7. C.M. Brown, Y. Liu, T. Yildirim, V.K. Peterson, C.J. Kepert, Hydrogen adsorption in HKUST-1: a combined inelastic neutron scattering and first-principles study, Nanotechnology, 2009, 20(20), 204025. DOI: 10.1088/0957-4484/20/20/204025

  8. M.B. Duriska, S.M. Neville, B. Moubaraki, J.A. Cashion, G.J. Halder, K.W. Chapman, C. Balde, J-F. Létard, K.S. Murray, C.J. Kepert, S.R. Batten, A nanoscale molecular switch triggered by thermal, light, and guest perturbation, Angew. Chem. Int. Ed., 2009, 48(14), 2549-2552. DOI: 10.1002/anie.200805178

2008
  1. G.J. Halder, K.W. Chapman, S.M. Neville, B. Moubaraki, K.S. Murray, J-F. Létard, C.J. Kepert, Elucidating the mechanism of a two-step spin transition in a nanoporous metal-organic framework, J. Am. Chem. Soc., 2008, 130(51), 17552-17562. DOI: 10.1021/ja8068038

  2. J.E. Beves, E.C. Constable, C.E. Housecroft, C.J. Kepert, M. Neuburger, D.J. Price, S. Schaffner, J.A. Zampese, Curly-curly, loop-loop: homoleptic metal(II) complexes of pyridinecarbaldehyde 4 '-(2,2':6',2''-terpyridyl) hydrazones and their coordination polymers, Dalton Trans., 2008, (47), 6742-6751. DOI: 10.1039/b810906k

  3. S.M. Neville, B.A. Leita, G.J. Halder, C.J. Kepert, B. Moubaraki, J-F. Létard, K.S. Murray, Understanding the two-step spin-transition phenomenon in iron(II) 1D chain materials, Chem. Eur. J., 2008, 14(32), 10123-10133. DOI: 10.1002/chem.200800886

  4. Y. Wu, A. Kobayashi, G.J. Halder, V.K. Peterson, K.W. Chapman, N. Lock, P.D. Southon, C.J. Kepert, Negative thermal expansion in the metal-organic framework material Cu3(1,3,5-benzenetricarboxylate)2, Angew. Chem. Int. Ed., 2008, 47(46), 8929-8932. DOI: 10.1002/anie.200803925

  5. S.S. Iremonger, P.D. Southon, C.J. Kepert, A nanoporous chiral metal-organic framework material that exhibits reversible guest adsorption, Dalton Trans., 2008, (44), 6103-6105. DOI: 10.1039/b816359f

  6. P. Yuan, P.D. Southon, Z.W. Liu, M.E.R. Green, J.M. Hook, S.J. Antill, C.J. Kepert, Functionalization of halloysite clay nanotubes by grafting with gamma-aminopropyltriethoxysilane, J. Phys. Chem. C, 2008, 112(40), 15742-15751. DOI: 10.1021/jp805657t

  7. J.E. Beves, D.J. Bray, J.K. Clegg, E.C. Constable, C.E. Housecroft, K.A. Jolliffe, C.J. Kepert, L.F. Lindoy, M. Neuburger, D.J. Price, S. Schaffner, F. Schaper, Expanding the 4,4'-bipyridine ligand: Structural variation in {M(pytpy)2}2+ complexes (pytpy=4'-(4-pyridyl)-2,2': 6',2''-terpyridine, M = Fe, Ni, Ru) and assembly of the hydrogen-bonded, one-dimensional polymer {[Ru(pytpy)(Hpytpy)]}n3n+, Inorg. Chim. Acta, 2008, 361(9-10), 2582-2590. DOI: 10.1016/j.ica.2007.10.040

  8. S.M. Neville, G.J. Halder, K.W. Chapman, M.B. Duriska, P.D. Southon, J.D. Cashion, J-F. Létard, B. Moubaraki, K.S. Murray, C.J. Kepert, Single-crystal to single-crystal structural transformation and photomagnetic properties of a porous iron(II) spin-crossover framework, J. Am. Chem. Soc., 2008, 130(9), 2869-2876. DOI: 10.1021/ja077958f

  9. A.E. Phillips, A.L. Goodwin, G.J. Halder, P.D. Southon, C.J. Kepert, Nanoporosity and exceptional negative thermal expansion in single-network cadmium cyanide, Angew. Chem. Int. Ed., 2008, 47(8), 1396-1399. DOI: 10.1002/anie.200704421

  10. J. Beves, E. Dunphy, E. Constable, C. Housecroft, C.J. Kepert, M. Neuburger, D. Price, S. Schaffner, Vectorial property dependence in bis{4'-(n-pyridyl)-2,2':6',2"- terpyridine}iron(II) and ruthenium(II) complexes with n = 2, 3 and 4, Dalton Trans., 2008, 3, 386-396. DOI: 10.1002/anie.200704421

Molecular Materials Group - School of Chemistry - The University of Sydney - NSW 2006 - Australia
Phone: +61-2-9351-7482 or +61-2-9351-5741 - Fax: +61-2-9351-3329